Influence of ball milling duration on the morphology,features of the structural-phase state and microhardness of 3Ni-Al powder mixture

The features of changes in the morphology, structural-phase state and microhardness of 3Ni-Al powder mixture after different duration of high-energy ball-milling have been studied. Three main stages of the evolution of the structural-phase state were revealed, which, corresponding to different duration of treatment, differ in the morphology of the powder mixture, distribution of components, phase compositions and the nature of changes in microhardness. It was found that under high-energy ball-milling conditions, the synthesis of intermetallic Ni₃Al and NiAl phases begins at much lower temperatures compared to the phase diagram. It is shown that an increase in the duration of high-energy ball-milling is accompanied by a transformation of the phase composition, the features of which determine the level of strengthening of the powder mixture studied.     

Effect of Ni and SAPO-34 co-additive on enhancing hydrogen storage performance of MgH2

The hydrogen storage performances of MgH₂ improved by the addition of Ni and SAPO-34 were studied in detail. The mixture of MgH₂ with Ni and SAPO-34 was a physical reaction as shown by the X-ray diffraction (XRD) results. The SAPO-34 and Ni were uniformly distributed on the surface of MgH₂. The thermodynamic and kinetic properties of 90MgH₂/5Ni/5SAPO-34 were investigated by differential scanning calorimetry (DSC) and pressure-composition-isothermal (PCI) methods. The results showed that the dehydrogenation activation energy of 90MgH₂/5Ni/5SAPO-34 decreased by 64.3 kJ/mol compared with that of MgH₂. In addition, the relationship between the value of dehydrogenation heat and hydrogen content was also investigated by in-situ calorimetry. The enthalpy value of each sample in the dehydrogenation processes were calculated by in-situ calorimetry measurement. The dehydrogenation enthalpies of as-milled MgH₂ and 90MgH₂/5Ni/5SAPO-34 were 63.2 kJ/mol H₂ and 53.6 kJ/mol H₂, respectively. Thus, the co-doping of Ni and SAPO-34 contributed significantly to decrease the thermodynamic stability and improve the hydrogen sorption kinetic properties of MgH₂.     

基于振动信号的深沟球轴承滚动体故障诊断研究

目前针对滚动轴承内、外圈故障的诊断方法较为有效,但难以诊断滚动体故障。针对这种情况,利用时域统计参数(有效值、峭度、脉冲因数、裕度因数)与Hilbert包络谱两种方法,对不同转速、负荷和故障程度情况下滚动体故障与正常状况的振动加速度数据进行比较分析,得出了滚动体故障难以诊断的原因,并给出了解决方法。     

掺氧化铝小球钢纤维混凝土的自修复性能研究

采用真空吸附法将环氧树脂和固化剂分别吸入薄壁氧化铝空心球中,用黏土进行球面密封,制得包含修复剂的小球。以钢纤维增强混凝土为基体,加入不同掺量的修复小球制备自修复混凝土试样,对其力学性能和自修复性能进行了测试。综合考虑修复效果和自修复混凝土自身的性能,自修复混凝土中钢纤维和修复小球的最佳掺量分别占水泥质量的1.5%和9%。     

新型化学铣切临时保护可剥性涂料

简要介绍了化学铣切临时保护可剥性涂料技术要求和研究进展,探讨了化学铣切原理及化学铣切临时保护可剥性涂料制备、应用工艺流程,自制的化学铣切临时保护可剥性涂料应用性能基本达到了国外同类产品的水平,是理想的更新换代产品。     

球磨法促进芳香醛与丙二睛的Knoevenagel缩合反应

以芳香醛和丙二睛为原料,NaCl为助磨剂,在无催化剂、无溶剂的条件下,通过球磨反应,以较高的收率合成了一系列Knoevenagel缩合反应产物,产物结构经过1H NMR和MS表征。本方法具有条件温和,后处理简单,环境友好,产率高等优点。     

球磨机失效钢球在线剔除装置及效能分析

球磨机是煤粉锅炉制粉系统的重要设备,适用范围广,可以磨制各种煤。磨煤机钢球在使用过程中会逐渐磨损,以致最后失效,如何将失效的钢球及时剔除,确保磨煤最佳出力一直以来是困扰我国电力生产的历史性问题。该文介绍一种球磨机失效钢球在线剔除装置及其应用情况。     

TC4铣削切屑形态与表面形貌特征

目的 对TC4铣削过程中锯齿状切屑的形成与对应产生的加工表面形貌特征进行研究,掌握钛合金TC4高速铣削加工切屑形态随铣削速度的变化规律,从而提高加工表面质量和效率。方法 基于有限元软件,建立钛合金TC4二维变厚度切削模型,通过仿真和铣削试验分析铣削速度对切屑形态的影响规律。利用超景深显微镜和PS50表面轮廓仪对TC4铣削过程中形成的切屑形态及工件加工表面形貌进行观测和分析,确定铣削加工TC4过程中铣削速度与切屑形态、工件表面形貌和表面粗糙度之间的关系。结果 铣削试验验证得出铣削力仿真值与试验值最大误差为9.86%,验证了二维变厚度切削模型的准确性。随着铣削速度从40 m/min增大到120 m/min,切屑形态由带状转变为锯齿状,且铣削力逐渐减小。同时,铣削速度由80 m/min增大到240 m/min时,切屑的锯齿化系数和剪切带内的剪切角均增大,而剪切带间距减小,TC4加工表面波纹加深、波纹间距变宽,并且伴随有大量韧窝出现,导致表面粗糙度值增大。结论 掌握锯齿状切屑几何特征与工件表面形貌随铣削速度的变化规律,以便在铣削加工TC4过程中对锯齿状切屑进行控制,对于提高工件加工表面质量和加...     

负压力角弧齿离合器铣齿机关键结构设计与加工仿真

负压力角弧齿离合器因承载能力强、啮合性能好、传动可靠性高等优势,被广泛应用于重型卡车驱动桥主减速器总成中。对负压力角弧齿离合器加工用的专用铣齿机的关键部件设计技术进行研究,构建铣齿加工数学模型,根据加工特点开展刀具箱、工件箱的结构功能分析,基于仿真软件建立等效机床模型,编制加工程序完成凸面齿与凹面齿的加工仿真与分析,验证了铣齿机设计方案的正确性。